AMX MAX-CSD 10 Manual do Utilizador

S1Supporting Information Ligand Flexibility and Framework Rearrangement in a New Family of Porous Metal-Organic Frameworks Samuel M. Hawxwell,a Guill

S10 Figure S6. TGA trace for 1 (heating under N2 at 5 ºC min-1 from room temperature to 600 ºC) Figure S7. TGA trace for 2 (heating under N2 at

S11 [2] SHELXTL 5.1, Bruker Analytical X-Ray Instruments, Inc., 1998. [3] (a) Shankland, K.; David, W. I. F.; Sivia, D. S. J. Mater. Chem. 1997, 7,

S2A mixture of dimethyl 5-hydroxyisophthalate (2.43 g, 11.6 mmol), 1,4-dibromobutane (1.08 g, 5.00 mmol) and K2CO3 (2.50 g, 18.1 mmol) were stirred i

S3 A mixture of dimethyl 5-hydroxyisophthalate (2.10 g, 10.0 mmol), trans-1,4-dibromobut-2-ene (1.05 g, 4.90 mmol), K2CO3 (2.21 g, 16.0 mmol) and di

S4Elemental Analysis: calcd for C20H18O11 (H42·H2O) C 55.30 % H 4.18 %, found C 55.49 % H 3.91 % 2.5 [Zn2(L1)(H2O)4]·2H2O (1) Zn(ClO4)2·6H2O (0.112

S5b (Å) 8.5113(17) 14.1157(7) c (Å) 9.827(2) 16.6631(8) α (°) 68.56(3) 66.602(1) β (°) 79.47(3) 87.138(1) γ (°) 86.62(3) 89.757(1) V (Å3) 5

S6 Figure S2. Alternative view of two-fold interpenetrated diamondoid network exhibited by 2. Colours as in Figure S1. Hydrogen atom, water molecule

S7structure was then refined against the data in the range 4 - 65 o 2θ using a restrained Rietveld method as implemented in TOPAS v3.1 [10], where on

S8 Figure S4. Crystal structure of 3 shown without water molecules in channels. Hydrogen atoms on coordinated water molecules are omitted (and were n

S9made phases, and by immersion of the reaction chamber into solid carbon dioxide contained in a cryogenic vessel (at 198 K) during isotherm measurem